Product ID:DZN 50W
MSDS Date:06/09/1989
FSC:6840
NIIN:00F008993
MSDS Number: BGZCW

CIBA-GEIGY CORP AGRICULTURAL DIV

410 SWING RD
GREENSBORO, NC 27419
US

Emergency Phone: 800-334-9481 OR 919-292-7100

Info Phone: 800-334-9481 OR 919-292-7100

Cage: 0267X

CIBA-GEIGY CORP, AGRICULTURAL DIV.

18300 GREENSBORO, NC 27419 US

Telephone: 800-888-8372 OR 800-334-9481

Cage: 8K340

DIAZINON

CAS: 333-41-5

RTECS: TF3325000

OSHA PEL 0.1 MG/CUM SKIN

ACGIH TLV: 0.1 MG/CUM (SKIN)

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

SILICA DIOXIDE, CRYSTALLINE QUARTZ, SAND (SUSPECTED HUMAN

CAS: 14808-60-7

RTECS: VV7330000

OSHA PEL 0.1 MG/CUM

ACGIH TLV: 0.1 MG/CUM RESP DUST

NUISANCE PARTICULATES

OSHA PEL 15 MG/CUM

ACGIH TLV: 10 MG/CUM

LD50 LC50 Mixture:ORAL LD50 (RATS): 1,550 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:SKIN/EYES: IRRITATION. INGESTION:
ASPIRATION INTO LUNGS, CHEMICAL PNEUMONIA. INHALATION:
CHOLINESTERASE INHIBITION W/HEADACHE, DIZZINESS, BLURRED VISION,
WEAKNESS, NAUSEA, CRAMPS, DIARRHEA, CHEST DISC OMFORT,
NERVOUSINESS, SWEATING, MIOSIS,TEARING, SALIVATION, CONVULSIONS,
CYANOIS, COMA, LOSS OF SPHINCTER CONTROL.
Explanation of Carcinogenicity:NONE

First Aid:INGESTION: IMMEDIATELY CONTACT PHYSICIAN. IF VICTIM IS FULLY
CONSCIOUS, GIVE LARGE QUANTITIES OF WATER & INDUCE VOMITING. NEVER
GIVE ANYTHING TO AN UNCONSCIOUS PERSON. GIVE ARTIFICIAL RESPIRATION
TO M AINTAIN BREATHING. SKIN: REMOVE CONTAMINATED CLOTHING. WASH
W/SOAP & WATER. EYE: FLUSH W/LARGE AMOUNTS OF WATER FOR 15 MINS.
GET MED ATT. INHALATION: REMOVE FROM CONTAMINATED ATMOSHPHERE. GET
MED ATT.

Extinguishing Media:DRY CHEMICALS, FOAM, CO2. EVACUATE NONESSENTIAL
PERSONNEL FROM THE AREA.
Fire Fighting Procedures:FIREFIGHTERS SHOULD WEAR FULL-FACE,
SELF-CONTAINED BREATHING APPARATUS & IMPERVIOUS CLOTHING.
Unusual Fire/Explosion Hazard:ORGANOPHOSPHATE INSECTICIDE. CONTAMINATED
BLDGS/AREA/EQUIPMENT MUST BE PROPERLY DECONTAMINATED. AUTOIGNITION
TEMPERATURE: >400C TECHNICAL

Spill Release Procedures:SWEEP UP PLACE IN APPROPRIATE CHEMICAL WASTE
CONTAINER. WASH AREA W/SATURATED SOLUTION OF SODIUM CARBONATE.
FLUSH AREA W/WATER. DON'T REUSE CONTAINER. WASTE WATER SHOULD BE
SENT TO A WATER TREATMENT F ACILITY. DON'T REUSE CONTAINER.
Neutralizing Agent:DON'T ATTEMPT TO NEUTRALIZE WITH CHEMICAL AGENTS.

Handling and Storage Precautions:KEEP OUT OF REACH OF CHILDREN.
CONTAINERS MUST BE STORED IN COOL, DRY, WELL VENTILATED AREA. STORE
AWAY FROM FOODSTUFFS.
Other Precautions:EATING, DRINKING & SMOKING SHOULD BE PREVENT IN
AREAS. THIS MATERIAL SHOULD BE HANDLED IN A WELL VENTILATED AREA.
DESTROY BY PERFORATION OR CRUSHING & BURYING IN A SAFE PLACE.

Respiratory Protection:WHERE ADEQUATE VENTILATION IS NOT AVAILABLE &
EXPOSURE TO EXCESSIVE DUST COULD OCCUR, WEAR A CONFLO II
(MSA)/OTHER APPROVED PESTICIDE RESPIRATOR.
Ventilation:THIS MATERIAL SHOULD BE HANDLED IN A WELL VENTILATED AREA.
Protective Gloves:RUBBER
Eye Protection:GOGGLES, SAFETY GLASSES
Other Protective Equipment:HOOD, SUITS & BOOTS.
Work Hygienic Practices:GOOD INDUSTRIAL HYGIENE PRACTICES. DESTROY
ARTICLES WHICH CAN'T BE WASHED.
Supplemental Safety and Health
BE SURE TO TELL THE PHYSICIAN THAT THE COMPOUND IS A CHOLINESTERASE
INHIBITOR. D-Z-N 50W IS AN ORGANIC PHOSPHATE INSECTICIDE. ATROPHINE
IS ANTIDOTAL FOR ORGANIC PHOSPHATE POISONING/SHOULD BE GIVEN I.V .
IN MULTIPLE DOSES OF ATROPINE SULFATEI.V. UNTIL THE PATIENT IS
ATROPINIZED. 2-PAM MAY BE GIVEN W/IN 36 HRS.

Spec Gravity:24 LBS/CU FT
Solubility in Water:40 MG/L AT 20C
Appearance and Odor:LIGHT BROWN POWDER, SLIGHT SULFUR LIKE ODOR

Stability Indicator/Materials to Avoid:YES
THIS IS NOT A COMBUSTIBLE MATERIALS.
Hazardous Decomposition Products:VARIOUS ALIPHATIC ORGANOPHOSPHATES,
SUBSTITUTED PYRIMIDINES & HYDROGEN CYANIDE.

Waste Disposal Methods:DISPOSAL OF MATERIAL, MUST BE BY METHODS
CONSISTENT W/LOCAL, STATE & FEDERAL HEALTH & ENVIRONMENTAL
REGULATIONS. A SPILL OF TWO POUNDS OF THIS MATERIAL IS REPORTABLE
TO THE NATIONAL RESPONSE CENTER.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.